Homochiral Pinene-Fused Cyclopentadienes. Synthesis and ?-Facially Selective Course of Diels-Alder Cycloadditions and Metallocene Formation

DOI: 10.1021/jo00230a015

Source and publish data:

Journal of Organic Chemistry p. 4732 - 4740 (1987)

Update date:2022-08-04

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Authors:

Paquette, Leo, A.

Gugelchuk, Melinda

McLaughlin, Mark L.

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Article abstract of DOI:10.1021/jo00230a015

Homochiral (1R)-(-)-9,9-dimethyltricyclo<6.1.1.0^2,6>deca-2,5-diene (3) has been synthesized and its Diels-Alder reaction with N-phenylmaleimide, p-benzoquinone, dimethyl acetylenedicarboxylate, and (Z)-1,2-bis(phenylsulfonyl)ethylene investigat

Full text of DOI:10.1021/jo00230a015

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