
Journal of Organic Chemistry p. 5532 - 5534 (1994)
Update date:2022-08-04
Topics: Total synthesis Chemical Synthesis Starting Materials Diterpenoid
Kan, Toshiyuki
Hosokawa, Seijiro
Nara, Shinji
Oikawa, Masato
Ito, Shinya
et al.
Total synthesis of (-)-grayanotoxin III (3), a unique tetracyclic diterpene isolated from the leaves of various plants of the family Ericaceae, has been successfully accomplished featuring the highly stereoselective cyclization reactions induced by SmI2.
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