Aldol Codensation via Germanium Enolates. Stereoselection Dictated by the Co-presence of Lithium Halides

DOI: 10.1039/c39880000802

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 802 - 804 (1988)

Update date:2022-07-29

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Authors:

Yamamoto, Yoshinori

Yamada, Jun-ichi

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Article abstract of DOI:10.1039/c39880000802

Trimethylgermanium enolates, prepared in situ from lithium enolates and trimethylgermanium halides, underwent a rapid aldol condensation with benzaldehyde to give the erythro-aldol predominantly, while the same enolates produced the threo-aldol preferenti

Full text of DOI:10.1039/c39880000802

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