Aldol Codensation via Germanium Enolates. Stereoselection Dictated by the Co-presence of Lithium Halides

DOI: 10.1039/c39880000802

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 802 - 804 (1988)

Update date:2022-07-29

Topics:

Authors:

Yamamoto, Yoshinori

Yamada, Jun-ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880000802

Trimethylgermanium enolates, prepared in situ from lithium enolates and trimethylgermanium halides, underwent a rapid aldol condensation with benzaldehyde to give the erythro-aldol predominantly, while the same enolates produced the threo-aldol preferenti

Full text of DOI:10.1039/c39880000802

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(C₆H₅)C(O)CH(CH₃)Ge(CH₃)3

Cas No:110614-56-7

R&D Labs maybe for 110614-56-7

Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China
Nanjing yieldpharma co.ltd

Contact:13813902930 025-52714267

Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
shanghai payne pharm co.,ltd.

Contact:+86-021-58123769

Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Chongqing KonAo Health Co.,Ltd

Contact:13687578375

Address:wuhan hubei china
HANGZHOU TOYOND BIOTECH CO., LTD

Contact:+86-571-86965177

Address:No. 189, Fengqi East Road, Hangzhou, China

Relevant to this article

The first synthesis of ent-agelasine F

Doi:10.1016/j.tet.2008.10.081
(2009)
Design, synthesis and evaluation of 3-methylene-substituted indolinones as antimalarials

Doi:10.1016/j.ejmech.2011.01.008
(2011)
Diphenyl cyancarbonimidate and dichlorodiphenoxymethane as synthons for the construction of heterocyclic systems of medicinal interest

Doi:10.1002/jhet.5570240153
(1987)
An Efficint Synthesis of 4-Aryl-1,2,3,4-terahydroisoquinolines

Doi:10.1039/c39870000191
(1987)
Doi:10.1039/jr9430000394
(1943)
Second-generation process for the hcv protease inhibitor biln 2061: A greener approach to ru-catalyzed ring-closing metathesis

Doi:10.1021/op800225f
(2009)

Article Doi