Journal of the American Chemical Society p. 17060 - 17061 (2009)
Update date:2022-08-04
Topics: Amines Kinetic Resolution Nucleophilic Catalysis Anion Binding
De, Chandra Kanta
Klauber, Eric G.
Seidel, Daniel
(Chemical Equation Presented) A new concept for asymmetric nucleophilic catalysis is presented. Acyl pyridinium salts derived from 4-(dimethylamino) pyridine (DMAP) and benzoic anhydride are rendered chiral via interaction with a chiral thiourea anion rec
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