Asymmetric cis-Hydroxylation via Epoxydation-Carboxylation: A Formal Synthesis of (+)-Citreoviral

DOI: 10.1016/S0040-4039(00)95732-0

Source and publish data:

Tetrahedron Letters p. 375 - 378 (1987)

Update date:2022-08-04

Topics:

Authors:

Trost, Barry M.

Lynch, John K.

Angle, Steven R.

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Article abstract of DOI:10.1016/S0040-4039(00)95732-0

Asymmetric epoxydation of tiglyl alcohol combined with Pd(0) catalyzed conversion to the vicinal diol with retention of configuration provides an efficient asymmetric synthesis of a key intermediate to (+)-citreoviral and related compounds.

Full text of DOI:10.1016/S0040-4039(00)95732-0

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