The insertion of silicon halides into oxiranes can be catalyzed by nucleophilic species. Common nucleophilic catalysts include Lewis bases such as tertiary amines (e.g., pyridine) or other nucleophilic substances. These catalysts can activate the silicon halide and increase the reaction rate.
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1-chloro-2-phenyl-2-(trimethylsiloxy)ethane
(R)-N-(1-phenylpentyl)benzamide
2-(trimethylsilyl)ethyl 3,3-difluoro-2-[(4-methoxyphenyl)imino]-5-hexenoate
