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Synthesis and Reactivity of Bis(o-nitrophenyl)platinum. X-Ray Crystal and Molecular Structure of

DOI: 10.1039/DT9860002215

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2215 - 2220 (1986)

Update date:2022-08-04

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Authors:

Vicente, JoseVicente, Jose

Chicote, Maria-TeresaChicote, Maria-Teresa

Martin, JoseMartin, Jose

Jones, Peter G.Jones, Peter G.

Fittschen, ChristaFittschen, Christa

Sheldrick, George M.Sheldrick, George M.

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Article abstract of DOI:10.1039/DT9860002215

Reaction of with K2 or PtCl2 (2:1) yields the complex .It reacts (i) with monodentate ligands L (PPh3, AsPh3, or pyridine) (1:1) to give complexes of the type or (ii) with monodentate L (PPh3, AsPh3, pyridine, or CO) (1:2) or bidentate ligands L2 (1:1) to give complexes .The crystal structure of shows both chelating and monodentate o-nitrophenyl groups.They show no significant differences in the bond lengths Pt-C <2.018(9) and 1.983(8) Angstroem, respectively> and N-C<1.446(11) and 1.468(12) Angstroem, respectively>.The co-ordinated oxygen atom has a longer N-O bond length <1.273(10) Angstroem> than the unco-ordinated one <1.221(10)>, cf. those in the unco-ordinated o-nitrophenyl group <1.220(10) and 1.230(11) Angstroem>.

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