ALKYL MIGRATION INCLUDING RING CONTRACTION FROM A MIGRATION ORIGIN BEARING A PHENYLTHIO (PhS) GROUP

DOI: 10.1016/S0040-4039(86)80050-8

Source and publish data:

Tetrahedron Letters p. 1069 - 1072 (1986)

Update date:2022-08-04

Topics:

Authors:

Hannaby, Malcolm

Warren, Stuart

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(86)80050-8

Alkyl shifts occur from tertary C atoms bearing a PhS group if PhS migration is prevented, but are retarded by the PhS group: the transition state has a cation-like migration terminus with little, if any, alkyl participation.

Full text of DOI:10.1016/S0040-4039(86)80050-8

Products guided by the article

Product name:(1SR,2SR,4SR)-4-tert-butyl-1-methyl-2-phenylthiocyclohexanol

Cas No:110977-16-7

R&D Labs maybe for 110977-16-7

HOST COUNTRY LIMITED

Contact:+852 83038667

Address:Room 1502, 15th Floor, SPA Centre,53-55 Lockhart Road, Wanchai, Hong Kong
WENZHOU M&C FOREIGN TRADE CO.,LTD.

Contact:+86-577-88862917

Address:No.8 Liming West Road,Wenzhou,zhejiang,China
Jinan Yufeng Bioengineering Co., Ltd.

Contact:+86-531-83130545/83130528/83130525/83130505

Address:Rm415,Building2,No19,Huaneng Road,Jinan, Shandong, China
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
AUSHUN PHARMACEUTICAL TECHNOLOGY CO,.LTD

Contact:+86-25-86883560 15951806178

Address:14 Dayingbi, Zhujiang Rd. East, Nanjing, Jiangsu, China.

Relevant to this article

Fragment-based discovery of JAK-2 inhibitors

Doi:10.1016/j.bmcl.2008.08.064
(2009)
Facile Access to 6-Methoxy-1,2,3,6-tetrahydro- and 4-Hydroxy-1,2,3,4-tetrahydropyridines by Electrochemical Haloalkoxylation-Dehydrohalogenation Sequence as a Key Operation

Doi:10.1055/s-1987-27901
(1987)
Selenium in Organic Synthesis: A Novel Route to 1-Phenylselenobutadienes and 1,4-Dicarbonyl Compounds

Doi:10.1055/s-1987-27865
(1987)
Facile one-pot synthesis of some novel thiazolylpyrazole derivatives with antifungal activity

Doi:10.1246/cl.130908
(2014)
Metabolism of sennosides by intestinal flora

Doi:10.1248/cpb.30.1338
(1982)
Synthesis of novel deuterium labelled derivatives of N-alkylated polyamines

Doi:10.1016/j.tet.2008.10.071
(2009)

Article Doi