
Journal of the Chemical Society. Perkin transactions I p. 2957 - 2961 (1990)
Update date:2022-08-04
Topics:
Bloodworth, A. J.
Crich, David
Melvin, T.
Photolysis of the O-acyl thiohydroxamate (2), precursor to the (Z)-cyclo-oct-4-enyl radical, in the presence of 18O2 and tertiary thiol provides the labelled hydroperoxide (8).The parent (Z)-cyclo-oct-4-enyl radical is shown to undergo transannular cyclization only under relatively forcing conditions.
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