Tetrahedron Letters p. 1345 - 1348 (1987)
Update date:2022-08-04
Topics:
Novi, Marino
Petrillo, Giovanni
Dell'Erba, Carlo
Diazosulfides 1 react with excess tetrabutylammonium cyanide in Me2SO under photon (sunlamp) or electron (Pt cathode) stimulation to give the corresponding nitriles.The results are interpreted on the basis of an SRN1 mechanism involving the (phenylthio)azo as nucleofugal group.
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Doi:10.1021/jo802594d
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(1989)
