Oxalyl Chloride as a One and Two Carbon Synthon. A Cyclic Carbonate with a Tetraoxapropellane Skeleton.

DOI: 10.1016/0040-4039(94)85313-4

Source and publish data:

Tetrahedron Letters p. 7359 - 7360 (1994)

Update date:2022-07-29

Topics:

Authors:

Grieneisen, Jean-Louis

Birbaum, Jean-Luc

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(94)85313-4

The chelation-directed reaction of bromomagnesium-2-tert-butylphenolate with oxalyl chloride yields the pentacyclic carbonate 5 along with the expected glyoxalyl chloride 2.Oxalyl chloride serves both as a C-acylation and esterification reagent.

Full text of DOI:10.1016/0040-4039(94)85313-4

Products guided by the article

Product name:(3-tert-Butyl-2-hydroxy-phenyl)-oxo-acetyl chloride

Cas No:111422-38-9

R&D Labs maybe for 111422-38-9

Changde Yungang Biotechnology Co., Ltd

website:http://www.cdyg.com

Contact:+86-736-7391178

Address:Qiaonan Industrial Park, Changde City, Hunan Province
Hunan Dinuo Pharmaceutical Co.,Ltd.

Contact:86-731-88280100*8561

Address:Bio-pharmaceutical industrial park, Liuyang, Hunan, China
Wuhan Benjamin Pharmaceutical Chemical Co.,Ltd

Contact:86-27-52341789

Address:Room 1518 B suite, optical valley time square, No 111 Guanshan Road, Hongshan District,Wuhan,Hubei Province,China.
LIAONING DMSO CHEMICALS CO.,LTD.

website:http://www.chinadmso.com

Contact:+86-427-6503033

Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Chengdu Green technology Co.,Ltd.

Contact:86-28-82608355

Address:C9 ,Economic Headquarters, Economic Development Zone, Chengdu.

Relevant to this article

N–H insertion reaction via an iron carbenoid from α-diazophenylpropionate and its application to the formal total synthesis of stizolobinic acid

Doi:10.1016/j.tet.2020.131619
(2020)
Stereoselective Synthesis of Octadeacpolyenoic Esters as an Insecticide

Doi:10.1246/bcsj.60.1103
(1987)
Synthesis and structures of palladium(II) and platinum(II) complexes containing heterocyclic thiolate ligands formed by cycloaddition reactions of coordinated azides

Doi:10.1139/V08-115
(2009)
O- AND C-STANNYLATION OF NITROALKANES

Doi:10.1016/S0022-328X(00)98973-3
(1987)
Pifa-mediated oxidative cyclization of 1-carbamoyl-1-oximylcycloalkanes: synthesis of spiro-fused pyrazolin-5-one N-oxides

Doi:10.1021/ol802952e
(2009)
A Convenient Synthesis of the Previously Unattainable 2-Arylselenazolopyridines

Doi:10.1055/s-1987-27943
(1987)

Article Doi