Oxalyl Chloride as a One and Two Carbon Synthon. A Cyclic Carbonate with a Tetraoxapropellane Skeleton.

DOI: 10.1016/0040-4039(94)85313-4

Source and publish data:

Tetrahedron Letters p. 7359 - 7360 (1994)

Update date:2022-07-29

Topics:

Authors:

Grieneisen, Jean-Louis

Birbaum, Jean-Luc

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Article abstract of DOI:10.1016/0040-4039(94)85313-4

The chelation-directed reaction of bromomagnesium-2-tert-butylphenolate with oxalyl chloride yields the pentacyclic carbonate 5 along with the expected glyoxalyl chloride 2.Oxalyl chloride serves both as a C-acylation and esterification reagent.

Full text of DOI:10.1016/0040-4039(94)85313-4

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