Oxalyl Chloride as a One and Two Carbon Synthon. A Cyclic Carbonate with a Tetraoxapropellane Skeleton.

DOI: 10.1016/0040-4039(94)85313-4

Source and publish data:

Tetrahedron Letters p. 7359 - 7360 (1994)

Update date:2022-07-29

Topics:

Authors:

Grieneisen, Jean-Louis

Birbaum, Jean-Luc

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(94)85313-4

The chelation-directed reaction of bromomagnesium-2-tert-butylphenolate with oxalyl chloride yields the pentacyclic carbonate 5 along with the expected glyoxalyl chloride 2.Oxalyl chloride serves both as a C-acylation and esterification reagent.

Full text of DOI:10.1016/0040-4039(94)85313-4

Products guided by the article

Product name:(3-tert-Butyl-2-hydroxy-phenyl)-oxo-acetyl chloride

Cas No:111422-38-9

R&D Labs maybe for 111422-38-9

Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
Beijing Harmony Chemical Co., Ltd.

Contact:86-010-84956928

Address:Room 207, Jin feng he B building, No 8 Xin Jie Kou Wai Street, Xi Cheng District, Beijing,PRC. 10008
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu
Lianyungang Ningkang Chemical Co., Ltd

Contact:.+86-518-88588008

Address:http://www.chemnk.com

Relevant to this article

N–H insertion reaction via an iron carbenoid from α-diazophenylpropionate and its application to the formal total synthesis of stizolobinic acid

Doi:10.1016/j.tet.2020.131619
(2020)
Stereoselective Synthesis of Octadeacpolyenoic Esters as an Insecticide

Doi:10.1246/bcsj.60.1103
(1987)
Synthesis and structures of palladium(II) and platinum(II) complexes containing heterocyclic thiolate ligands formed by cycloaddition reactions of coordinated azides

Doi:10.1139/V08-115
(2009)
O- AND C-STANNYLATION OF NITROALKANES

Doi:10.1016/S0022-328X(00)98973-3
(1987)
Pifa-mediated oxidative cyclization of 1-carbamoyl-1-oximylcycloalkanes: synthesis of spiro-fused pyrazolin-5-one N-oxides

Doi:10.1021/ol802952e
(2009)
A Convenient Synthesis of the Previously Unattainable 2-Arylselenazolopyridines

Doi:10.1055/s-1987-27943
(1987)

Article Doi