REGIOSELECTIVITY OF DIELS-ALDER ADDITIONS OF 1-ACETYLVINYL ARENECARBOXYLATES

DOI: 10.1016/S0040-4039(01)81009-1

Source and publish data:

Tetrahedron Letters p. 865 - 868 (1987)

Update date:2022-08-02

Topics:

Authors:

Aguilar, Raul

Reyes, Alicia

Tamariz, Joaquin

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Article abstract of DOI:10.1016/S0040-4039(01)81009-1

The Diels-Alder addition of "captodative" dienophiles 1-acetylvinyl arenecarboxylates 1b,1d and 1e to 1- and 2-substituted dienes was found highly regioselective.The rate and regioselectivity of this reaction were improved by Lewis acid catalysis.

Full text of DOI:10.1016/S0040-4039(01)81009-1

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