ChemCatChem p. 371 - 375 (2018)
Update date:2022-08-02
Topics:
Ouyang, Jia-Sheng
Li, Yan-Fang
Huang, Fei-Dong
Lu, Dong-Dong
Liu, Feng-Shou
A series of Pd–PEPPSI complexes were designed and synthesized. The relationship between catalyst structure and properties was systematically investigated. It was revealed that “bulky-yet-flexible” C3 bearing ancenaphthyl backbone was a highly efficient precatalyst and could be successfully employed in Suzuki–Miyaura reactions of (hetero)aryl chlorides with (hetero)arylboronic acids at a low palladium loading in the presence of a weak inorganic base in air.
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