Chemistry Letters p. 963 - 966 (1987)
Update date:2022-08-04
Topics:
Naruta, Yoshinori
Maruyama, Kazuhiro
In the presence of BF3*OEt2, reaction of allylstannanes with vinyl epoxides gives 1,2 or 1,4 addition products in good yield, depending on the substitution at the olefinic terminus.In either case regioselectivity is extremely high.The 1,2 adduct is applied to the elongation of a prenyl unit in polyprenyl compounds.
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Doi:10.1016/S0040-4039(00)96042-8
(1987)Doi:10.1016/S0040-4039(00)80131-8
(1988)Doi:10.1002/jhet.717
(2011)Doi:10.1002/ardp.19582911108
(1958)Doi:10.1002/recl.19770960708
(1977)Doi:10.1016/S0040-4039(01)80997-7
(1987)