Regioselective Silylolefination of Allylic Dithioacetals. Stereoselective Synthesis of 1-(Trimethylsilyl)butadienes

DOI: 10.1021/jo00258a047

Source and publish data:

Journal of Organic Chemistry p. 5582 - 5584 (1988)

Update date:2022-07-31

Topics:

Authors:

Ni, Zhi-Jie

Luh, Tien-Yau

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00258a047

1-(Trimethylsilyl)butadienes are regioselectively and stereoselectively synthesized in good to excellent yields from the reactions of allylic dithioacetals and <(trimethylsilyl)methyl>magnesium chloride in the presence of 5 mol percent of NiCl2(PPh3)2 in

Full text of DOI:10.1021/jo00258a047

Products guided by the article

Product name:Silane, trimethyl(4-phenyl-1,3-pentadienyl)-

Cas No:112371-23-0

R&D Labs maybe for 112371-23-0

Jinan Hongfangde Pharmatech Co.LTD

Contact:0531-88870908

Address:F Bldg,750#,Shunhua Rd,New&High-tech Zone,Jinan,Shandong,China 250101
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang
Shangyu Sanhechemicals Co.,LTD.

Contact:86-0571-56696839

Address:Num.2952,Nanhuan Road,Binjiang District,Hangzhou,China
Zhejiang Homart Chemical & Technology Co., Ltd.(expird)

Contact:13587107601

Address:Cuijiatianpu,Quzhou, Zhejiang, China (Mainland)
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China

Relevant to this article

N → N acyl group migration in N-acylpyrazoles: Isomerization of 1,4-diacyl-5-methyl-1H-pyrazoles to 1,4-diacyl-3-methyl-1H-pyrazoles

Doi:10.1134/S1070428017030125
(2017)
Lead identification to generate 3-cyanoquinoline inhibitors of insulin-like growth factor receptor (IGF-1R) for potential use in cancer treatment

Doi:10.1016/j.bmcl.2008.11.037
(2009)
Ti (IV) complexes of some heterocyclic ligands synthesis, characterization and ethylene polymerization activity

Doi:10.13005/ojc/320177
(2016)
Doi:10.1039/jr9570002999
(1957)
Truly catalytic and chemoselective cleavage of benzylidene acetal with phosphomolybdic acid supported on silica gel

Doi:10.1002/ejoc.200800963
(2008)
A NEW ROUTE TO 3-HETEROARYLINDOLES

Doi:10.1016/S0040-4020(01)90049-3
(1987)

Article Doi