Tetrahedron p. 5607 - 5620 (1986)
Update date:2022-08-03
Topics:
Alexakis, A.
Jachiet, D.
Normant, J. F.
In the presence of BF3 the reaction rate of organocopper and cuprate reagents with poorly reactive epoxides is dramatically enhanced.Lithium organocuprates are the best choice among the various organocopper and cuprate reagents tested.Even the dimesityl cyanocuprate is able to react with cyclohexene oxide in excellent yield.No products of cationic rearrangements are observed.The reaction with various epoxides shows a complete stereochemical (pure anti opening) and regiochemical control (attack on the less hindered side of the epoxide).
View MoreZhejiang Sucon Silicone Co.,Ltd
Contact:+86-575-88046692
Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Hangzhou Yanshan Chemical Co.,Ltd.
Contact:86-571- 87698076
Address:Room 1001, #1 Building, Zhongtian MCC, No.2 Youzhinong, Wenyi West Road, Xihu District, Hangzhou, China
Contact:86-607-68073220
Address:1 ave na road jiahua st
ShangHai Original Economy-Trade Develop Co.,Ltd.,
Contact:86-21-68552131
Address:shanghai
Jinan Baozhao Pharmaceutical Co., Ltd
Contact:0086-531-86397156 82371858 82371868
Address:Huaneng Road, Jinan, Shandong ,China
Doi:10.1021/ja00212a052
(1988)Doi:10.1021/ja01097a032
(1953)Doi:10.1021/es00007a022
(1995)Doi:10.1055/s-0034-1380166
(2015)Doi:10.1515/znb-2016-0017
(2016)Doi:10.1016/S0040-4020(97)00491-2
(1997)
