1-ACETOXY AND 1-SILYLOXY-1,3-DIENES VIA REDUCTIVE HOMOLOGATION OF α,β-UNSATURATED ESTERS

DOI: 10.1016/S0040-4039(00)95441-8

Source and publish data:

Tetrahedron Letters p. 2463 - 2466 (1987)

Update date:2022-08-04

Topics:

Authors:

Kowalski, Conrad J.

Lal, G. Sankar

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Article abstract of DOI:10.1016/S0040-4039(00)95441-8

α,β-Unsaturated esters (1) are stereospecifically converted in a one-pot preparation into 1-oxygenated-E,E-dienes (4).This reductive homologation proceeds via lithium hydride reduction of the ene ynolate anion (2) to the dienolate anion 3, affording 1-acetoxy- or 1-silyloxy-1,3-dienes in yields of about 45-55percent.

Full text of DOI:10.1016/S0040-4039(00)95441-8

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