Tetrahedron Letters p. 5033 - 5036 (1987)
Update date:2022-07-29
Topics:
Buisson, Didier
Henrot, Serge
Larcheveque, Marc
Azerad, Robert
The reduction of 4-O-benzyl-2-methyl-3-oxo-butyrate esters by several fungal strains produces predominantly (2S,3R)-anti-hydroxyesters in high optical purity.The corresponding (2R,3R)-syn isomer was obtained, with other strains, only in mixture with the anti isomer.These esters are useful precursors for chiral 2-methyl-3-hydroxy-butyrolactone synthons.
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Doi:10.1021/acs.joc.9b01913
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