SULFONE MEDIATED SYNTHESIS OF CYCLOPENTADIENONE EPOXIDES FROM 10-OXATRICYCLO /5.2.1.02,6/ DECADIENONES . A CONVENIENT ROUTE TO epi-PENTENOMYCINS

DOI: 10.1016/S0040-4039(00)95362-0

Source and publish data:

Tetrahedron Letters p. 1329 - 1332 (1987)

Update date:2022-08-04

Topics:

Authors:

Klunder, A. J. H.

Houwen-Claassen, A. A. M.

Kooy, M. G.

Zwanenburg, B.

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Article abstract of DOI:10.1016/S0040-4039(00)95362-0

Sulfonylmethylation of 10-oxatricyclodecadienone 6 leads to sulfone 4 which forms the key intermediate in the synthesis of 5-alkoxymethylcyclopentadienone epoxides 5.Acid catalyzed hydrolysis of 5 followed by acylation affords epi-pentenomycin derivates 1

Full text of DOI:10.1016/S0040-4039(00)95362-0

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