RUTHENIUM CATALYZED OXIDATION OF CYANOHYDRINS TO ACYL CYANIDES USEFUL REAGENTS FOR SELECTIVE N-BENZOYLATION OF AMINOALCOHOLS

DOI: 10.1016/S0040-4039(00)61966-4

Source and publish data:

Tetrahedron Letters p. 925 - 928 (1985)

Update date:2022-08-04

Topics:

Authors:

Murahashi, Shun-ichi

Naota, Takeshi

Nakajima, Nobuyuki

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Article abstract of DOI:10.1016/S0040-4039(00)61966-4

Ruthenium catalyzed oxidation of cyanohydrins with tert-butyl hydroperoxide gives the corresponding acyl cyanides in good to excellent yields.Acyl cyanides thus obtained are useful reagents for selective N-benzoylation of aminoalcohols.

Full text of DOI:10.1016/S0040-4039(00)61966-4

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