C-CENTRED OPTICALLY ACTIVE ORGANOSILANES,2. APPLICATION TO ENANTIOSELECTIVE ALLYLATION OF CARBONYL COMPOUNDS.

DOI: 10.1016/S0040-4039(00)95889-1

Source and publish data:

Tetrahedron Letters p. 969 - 972 (1987)

Update date:2022-07-29

Topics:

Authors:

Coppi, Laura

Mordini, Alessandro

Taddei, Maurizio

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Article abstract of DOI:10.1016/S0040-4039(00)95889-1

C-Centred optically active allylsilanes react with carbonyl compounds in presence of Lewis acids to give the corresponding homoallyl alcohols with ee varying from 21 to 56percent.The role of the Lewis acid is crucial for a correct development of the reaction; different procedures are tested and the results compared.

Full text of DOI:10.1016/S0040-4039(00)95889-1

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