C-CENTRED OPTICALLY ACTIVE ORGANOSILANES,2. APPLICATION TO ENANTIOSELECTIVE ALLYLATION OF CARBONYL COMPOUNDS.

DOI: 10.1016/S0040-4039(00)95889-1

Source and publish data:

Tetrahedron Letters p. 969 - 972 (1987)

Update date:2022-07-29

Topics:

Authors:

Coppi, Laura

Mordini, Alessandro

Taddei, Maurizio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95889-1

C-Centred optically active allylsilanes react with carbonyl compounds in presence of Lewis acids to give the corresponding homoallyl alcohols with ee varying from 21 to 56percent.The role of the Lewis acid is crucial for a correct development of the reaction; different procedures are tested and the results compared.

Full text of DOI:10.1016/S0040-4039(00)95889-1

Products guided by the article

Product name:2H-Pyran, 4-chlorotetrahydro-2,6-dipropyl-

Cas No:112852-91-2

R&D Labs maybe for 112852-91-2

Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
Jiaozuo Zhongwen Trading Coporation Limited

Contact:--

Address:East Renmin Road
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP
Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China

Relevant to this article

N,N-Di-n-propylserotonin: Binding at serotonin binding sites and a comparison with 8-hydroxy-2-(di-n-propylamino)tetralin

Doi:10.1021/jm00399a031
(1988)
Reaction of alkyl-3-nitro- and -3-bromo-3-nitroacrylates with 2-(2-nitroethenyl)furan

Doi:10.1134/S1070363208050216
(2008)
Cascade cyclization of 1,2-diamino-4-phenylimidazole with aromatic aldehydes and Meldrum's acid

Doi:10.1016/j.mencom.2008.05.010
(2008)
A Novel Transformation of Four Aldoses to Some Optically Pure Pseudohexopyranoses and a Pseudopentofuranose, Carboxylic Analogues of Hexopyranoses and Pentofuranose. Synthesis of Derivatives of (1S,2S,3R,4S,5S)-, (1S,2S,3R,4R,5S)-, (1R,2R,3R,4R,5S)-, (1S,

Doi:10.1021/jo00386a011
(1987)
Elemental-Sulfur-Incorporated Cyclizations of Pyrrolidines Leading to Thienopyrroles

Doi:10.1021/acs.joc.0c01363
(2020)
Evaluation and comparison of the antioxidative potency of various carbohydrates using different methods

Doi:10.1021/jf804020u
(2009)

Article Doi