Concise asymmetric synthesis of (-)-deoxoprosophylline

DOI: 10.1016/j.tetasy.2008.12.014

Source and publish data:

Tetrahedron Asymmetry p. 2731 - 2734 (2008)

Update date:2022-08-05

Topics:

Authors:

Liu, Ru-Cheng

Wei, Jin-Hu

Wei, Bang-Guo

Lin, Guo-Qiang

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Article abstract of DOI:10.1016/j.tetasy.2008.12.014

An efficient asymmetric synthesis of the 2-hydroxymethyl 3,6-disubstituted piperidine alkaloid, (-)-deoxoprosophylline, is described. The key step of this route is the SmI₂-mediated cross-coupling of chiral N-tert-butanesulfinyl imine 9 with al

Full text of DOI:10.1016/j.tetasy.2008.12.014

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