A NOVEL APPROACH TO α-KETO ACID DERIVATIVES VIA PALLADIUM-CATALYZED ARYLATION AND VINYLATION OF METHYL α-METHOXYACRYLATE

DOI: 10.1016/S0040-4039(00)96279-8

Source and publish data:

Tetrahedron Letters p. 3039 - 3042 (1987)

Update date:2022-08-05

Topics:

Authors:

Cacchi, Sandro

Ciattini, Pier Giuseppe

Morera, Enrico

Ortar, Giorgio

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Article abstract of DOI:10.1016/S0040-4039(00)96279-8

Methyl α-methoxyacrylate reacts stereoselectively with aryl iodides and vinyl triflates under palladium catalysis to give enol ethers of arylpyruvates and of β,γ-unsaturated α-keto esters in good to moderate yields.

Full text of DOI:10.1016/S0040-4039(00)96279-8

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