Tetrahedron p. 2311 - 2316 (1987)
Update date:2022-07-29
Topics:
Pericas, Miquel A.
Serratosa, Felix
Valenti, Eduard
The synthesis of tert-butoxyethyne (1a) and (1-adamantyloxy)ethyne (1b) has been performed by a three step sequence starting from ethyl vinyl ether.Overall yields are 34 and 67percent, respectively.The process is insensitive to the steric hindrance of the tertiary alcohol used and can be conveniently modified for the preparation of 1-tert-alkoxy-1-alkynes in high yield, without isolation of the intermediate 1-tert-alkoxyethyne.
View MoreJiangxi Global Natural Spice Co., Ltd.
website:https://www.jxhqxl.com/
Contact:+86-796-8106598
Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Contact:+86-28-88523492
Address:714rooms of Time Square, Pujiang County
Shanghai Dianyang Industry Co.,ltd
Contact:+86 21 6492 4669
Address:Chejing RD, Songjiang District, Shanghai, China
website:http://www.fwdchem.com
Contact:86-21-54450828
Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai
Contact:+86-532-80762375
Address:No. 6, Hongkong Middle Road, Qingdao, China
Doi:10.1007/s11172-007-0400-x
(2007)Doi:10.1016/S0040-4020(01)86890-3
(1987)Doi:10.1246/bcsj.60.3068
(1987)Doi:10.1007/s10593-008-0026-4
(2008)Doi:10.1016/j.bmcl.2008.12.008
(2009)Doi:10.1021/acs.orglett.8b00276
(2018)
