Stereoselective Total Synthesis of (+/-)-Subergorgic Acid, a New Type of Angular Triquinane Sesquiterpene

DOI: 10.1021/jo00243a006

Source and publish data:

Journal of Organic Chemistry p. 1623 - 1628 (1988)

Update date:2022-07-30

Topics:

Authors:

Iwata, Chuzo

Takemoto, Yoshiji

Doi, Miyako

Imanishi, Takeshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00243a006

The first stereoselective total synthesis of (+/-)-subergorgic acid (4), a new angular triquinane sesquiterpene isolated from a gorgonian coral, has been achieved by beginning with rel-(2R,5R,10S)-2-hydroxy-6,10-dimethylspiro<4.5>dec-6-en-8-one (5).Transf

Full text of DOI:10.1021/jo00243a006

Products guided by the article

Product name:rel-(5R,6S,10S)-6-<2-(methoxymethoxy)ethyl>-6,10-dimethyl-3-(phenylthio)spiro<4.5>dec-7-en-2-one

Cas No:113353-11-0

R&D Labs maybe for 113353-11-0

Shanghai WinTide BioTechnology Co.,Ltd

Contact:86-21-37100630

Address:No. 908 Yunhe Road, Fengxian district, Shanghai
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
SHANDONG AONA CHEMICAL CO.,LTD.

Contact:86-532-85762926

Address:LIUYUAN TOWN, ZAOZHUANG CITY, SHANGDONG PROVINCE.
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
TIANJIN FESTO CHEMICAL CO.,LTD(expird)

Contact:86-22-25814570

Address:No.12th,5th Ave.,TEDA,Tianjin,China

Relevant to this article

Asymmetric Synthesis of Diarylmethyl Sulfones by Palladium-Catalyzed Enantioselective Benzylic Substitution: A Remarkable Effect of Water

Doi:10.1002/chem.201800744
(2018)
The effect of the nature of the substituent at the nitrogen atom on transformations of 3-bromo-2,2,6,6-tetramethyl-4-piperidinone and its 1-hydroxy and 1-oxyl derivatives under conditions of the Favorsky rearrangement

Doi:10.1007/BF02496215
(1997)
An optimised synthesis of 2-[2,3-Bis(tert -butoxycarbonyl)guanidino] ethylamine

Doi:10.1055/s-0031-1290698
(2012)
Kinetics of action of a two-stage pro-inhibitor of serine β-lactamases

Doi:10.1021/bi400873r
(2013)
Synthesis, Coloration, and Crystal Structure of the "Dibasic" Chromoacerand-Piperazine 1:1 Salt Complex

Doi:10.1021/ja00217a047
(1988)
Characterization of stereoisomeric 5-(2-nitro-1-phenylethyl)furan-2(5H)-ones by computation of ¹H and ¹³C NMR chemical shifts and electronic circular dichroism spectra

Doi:10.1002/mrc.5073
(2021)

Article Doi