Stereoselective Total Synthesis of (+/-)-Subergorgic Acid, a New Type of Angular Triquinane Sesquiterpene

DOI: 10.1021/jo00243a006

Source and publish data:

Journal of Organic Chemistry p. 1623 - 1628 (1988)

Update date:2022-07-30

Topics:

Authors:

Iwata, Chuzo

Takemoto, Yoshiji

Doi, Miyako

Imanishi, Takeshi

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Article abstract of DOI:10.1021/jo00243a006

The first stereoselective total synthesis of (+/-)-subergorgic acid (4), a new angular triquinane sesquiterpene isolated from a gorgonian coral, has been achieved by beginning with rel-(2R,5R,10S)-2-hydroxy-6,10-dimethylspiro<4.5>dec-6-en-8-one (5).Transf

Full text of DOI:10.1021/jo00243a006

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