Insertion of Ketene and Diphenylketene to the Pnictogen-Heteroatom Bonds

DOI: 10.1246/bcsj.60.1564

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1564 - 1566 (1987)

Update date:2022-08-04

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Authors:

Ando, Fumio

Kohmura, Yoshihiko

Koketsu, Jugo

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Article abstract of DOI:10.1246/bcsj.60.1564

Ketene and diphenylketene insert across the heteroatom-metal bond of amino-, alkoxy-, and alkylthio-pnictogens, R_3-nMX_n, to give the corresponding α-metallated acetamides, esters, and thioesters, R_3-nM(CH2COX)_n and R_3-nM(CPh2COX)_n (M=As, Sb, Bi; X=NR2, OR, SR; n=1,3), respectively.

Full text of DOI:10.1246/bcsj.60.1564

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