Bulletin of the Chemical Society of Japan p. 1564 - 1566 (1987)
Update date:2022-08-04
Topics:
Ando, Fumio
Kohmura, Yoshihiko
Koketsu, Jugo
Ketene and diphenylketene insert across the heteroatom-metal bond of amino-, alkoxy-, and alkylthio-pnictogens, R3-nMXn, to give the corresponding α-metallated acetamides, esters, and thioesters, R3-nM(CH2COX)n and R3-nM(CPh2COX)n (M=As, Sb, Bi; X=NR2, OR, SR; n=1,3), respectively.
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