Iminium Ions as Initiators and Allylsilanes as Terminators in Polyolefin Cyclizations: Total Synthesis of (+/-)-Yohimbone via A Vinylogous Aminomethano Desilylation

DOI: 10.1039/c39870000185

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 185 - 186 (1987)

Update date:2022-08-04

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Authors:

Grieco, Paul A.

Fobare, William F.

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Article abstract of DOI:10.1039/c39870000185

A syntyheses of (+/-)-yohimbone has been realized via a concerted iminium ion-induced polyolefin cyclization terminated by an allylsilane.

Full text of DOI:10.1039/c39870000185

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