Regio- and Stereoselective Synthesis of Allylic and Homoallylic Alcohols by the Reductive Desulfonylation of Allylic Sulfone Derivatives. Application to the Syntheses of (+/-)-Lavandulol and Isolavandulol

DOI: 10.1246/cl.1987.707

Source and publish data:

Chemistry Letters p. 707 - 710 (1987)

Update date:2022-08-04

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Authors:

Inomata, Katsuhiko

Igarashi, Susumu

Mohri, Mitsunobu

Yamamoto, Taku

Kinoshita, Hideki

Kotake, Hiroshi

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Article abstract of DOI:10.1246/cl.1987.707

Regio- and stereoselective desulfonylation of β-tosylhomoallylic alcohols provided a convenient method for the preparation of allylic and homoallylic alcohols. (+/-)-Lavandulol and isolavandulol were synthesized in excellent yields by this method.

Full text of DOI:10.1246/cl.1987.707

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