POLYFLUOROARYL ORGANOMETALLIC COMPOUNDS. XVII. 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYLLITHIUM, A STERICALLY CROWDED SYSTEM

DOI: 10.1016/0022-328X(87)80383-2

Source and publish data:

Journal of Organometallic Chemistry p. 13 - 24 (1987)

Update date:2022-07-30

Topics:

Authors:

Carr, G. E.

Chambers, R. D.

Holmes, T. F.

Parker, P. G.

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Article abstract of DOI:10.1016/0022-328X(87)80383-2

A lithium derivative (3) is generated from 1,3,5-tris(trifluoromethyl)benzene (2) and is shown to be remarkably stable.It is shown that 2 is less acidic than pentafluorobenzene, in competition for butyllithium.A preliminary survey of reactivity shows that

Full text of DOI:10.1016/0022-328X(87)80383-2

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