POLYFLUOROARYL ORGANOMETALLIC COMPOUNDS. XVII. 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYLLITHIUM, A STERICALLY CROWDED SYSTEM

DOI: 10.1016/0022-328X(87)80383-2

Source and publish data:

Journal of Organometallic Chemistry p. 13 - 24 (1987)

Update date:2022-07-30

Topics:

Authors:

Carr, G. E.

Chambers, R. D.

Holmes, T. F.

Parker, P. G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(87)80383-2

A lithium derivative (3) is generated from 1,3,5-tris(trifluoromethyl)benzene (2) and is shown to be remarkably stable.It is shown that 2 is less acidic than pentafluorobenzene, in competition for butyllithium.A preliminary survey of reactivity shows that

Full text of DOI:10.1016/0022-328X(87)80383-2

Products guided by the article

Product name:Mercury, bis[2,4,6-tris(trifluoromethyl)phenyl]-

Cas No:114071-31-7

R&D Labs maybe for 114071-31-7

Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

website:http://www.jlpharms.com

Contact:86-571-86982636

Address:Rm A606, Fuyi Center, jianqiao street
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District
NOVASYNCS CO., LTD

Contact:0512-63006287

Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA

Relevant to this article

X-RAY CRYSTAL STRUCTURE AND REACTIONS OF 2-CYANO-1,3-DIBENZOYL-2,3-DIHYDROBENZIMIDAZOLE, A NOVEL REISSERT COMPOND

Doi:10.1016/0040-4039(91)80670-2
(1991)
A mild and efficient synthesis of aryl sulfones from aryl chlorides and sulfinic acid salts using microwave heating

Doi:10.1055/s-0031-1289541
(2011)
Functionality Transfer from C6 to C8 in Sesquiterpenes. Synthesis of 8-epi-Ivangustin and 8-epi-Isoivangustin from Santonin

Doi:10.1021/jo00021a040
(1991)
Tris(phenylimido) complexes of tungsten: Preparation and properties of the d⁰ W(=NR)₃ functional group

Doi:10.1021/ja00016a090
(1991)
The discovery of tetrahydropyridine analogs as hNav1.7 selective inhibitors for analgesia

Doi:10.1016/j.bmcl.2017.03.043
(2017)
Antimicrobial activity of newly synthesized methylsulfanyl- triazoloquinazoline derivatives

Doi:10.1111/jphp.12039
(2013)

Article Doi