Oxymetylation. 21. Regioselectivity, Rearrangement, and Direct 1,2-Dioxolane Formation in the Peroxymercuriation of cis- and trans-1,2-Diphenylcyclopropane

DOI: 10.1021/jo00247a002

Source and publish data:

Journal of Organic Chemistry p. 2668 - 2674 (1988)

Update date:2022-08-02

Topics:

Authors:

Bloodworth, A.J.

Lampman, G.M.

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Article abstract of DOI:10.1021/jo00247a002

The regiochemistry and stereochemistry of the peroxymercuriation of trans- and cis-1,2-diphenylcyclopropane (1a,b) have been determined.The trans isomer reacted exclusively by 1,3-bond scission to give the threo and erythro γ-peroxymercurials (3a,b) along

Full text of DOI:10.1021/jo00247a002

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