Oxymetylation. 21. Regioselectivity, Rearrangement, and Direct 1,2-Dioxolane Formation in the Peroxymercuriation of cis- and trans-1,2-Diphenylcyclopropane

DOI: 10.1021/jo00247a002

Source and publish data:

Journal of Organic Chemistry p. 2668 - 2674 (1988)

Update date:2022-08-02

Topics:

Authors:

Bloodworth, A.J.

Lampman, G.M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00247a002

The regiochemistry and stereochemistry of the peroxymercuriation of trans- and cis-1,2-diphenylcyclopropane (1a,b) have been determined.The trans isomer reacted exclusively by 1,3-bond scission to give the threo and erythro γ-peroxymercurials (3a,b) along

Full text of DOI:10.1021/jo00247a002

Products guided by the article

Product name:3-(tert-butylperoxy)-1,3-diphenylpropyl acetate

Cas No:114424-54-3

R&D Labs maybe for 114424-54-3

Shanghai SMEC Trading Co., Ltd.

website:http://www.shanghaismec.com

Contact:+86-21-68811293

Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
Tianjin SPHINX SCIENTIFIC LAB.

Contact:+86-022-66211289

Address:Tianda high-tech Park. No.80,the 4th Avenue
Taimai Sanluck Pharmaceutical Co.,Ltd

Contact:86-592-7662921

Address:8D,No.186,Huarong Road,Huli,Xiamen,China
Hangzhou Donglou Bio-nutrient Co., Ltd.

Contact:+86-571-82225795,13967112289

Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang

Relevant to this article

Synthesis and characterization of manganese and iron complexes supported by multidentate [N₂P₂] ligands

Doi:10.1039/b821954k
(2009)
Phase-Vanishing Method with Acetylene Evolution and Its Utilization in Several Organic Syntheses

Doi:10.1021/acs.orglett.5b00827
(2015)
ANTIFIBRINOLYTIC ACTIVITY OF NICOTINIC ACID CONJUGATES WITH 6-AMINOHEXANOIC, p-AMINOMETHYLBENZOIC, AND trans-4-AMINOMETHYLCYCLOHEXANECARBOXYLIC ACIDS

Doi:10.1007/BF00757485
(1987)
A facile and practical copper powder-catalyzed, organic solvent-and ligand-free ullmann amination of aryl halides

Doi:10.1021/jo102169t
(2011)
[PdCl(TeMe₂)₃](BAr^F) - The first structurally characterized palladium(II) complex with TeMe₂ ligands

Doi:10.1002/zaac.200700575
(2008)
SYNTHESIS OF (2-DEOXY-α-D-GLYC-2-ENOPYRANOSYL)ARENES BY STEREOSPECIFIC CONJUGATE-ADDITION OF ORGANOCOPPER REAGENTS TO PERACYLATED HEX-1-ENOPYRAN-3-ULOSES

Doi:10.1016/S0008-6215(00)90892-9
(1987)

Article Doi