Rhodium Carbenoid Induced Cycloadditions of Substituted 1-Diazo-2,5-pentanediones

DOI: 10.1021/jo00247a051

Source and publish data:

Journal of Organic Chemistry p. 2875 - 2877 (1988)

Update date:2022-08-02

Topics:

Authors:

Padwa, Albert

Fryxell, Glen E.

Zhi, Lin

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Article abstract of DOI:10.1021/jo00247a051

Treatment of substituted 1-diazo-2,5-pentadienones with rhodium(II) acetate results in cyclization of the intermediate rhodium carbenoid to give a six ring carbonyl ylide which readily undergoes both inter- and intramolecular dipolar cycloadditions.

Full text of DOI:10.1021/jo00247a051

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