Geminal Selectivity in Singlet Oxygen Reactions

DOI: 10.1021/jo00248a044

Source and publish data:

Journal of Organic Chemistry p. 3124 - 3125 (1988)

Update date:2022-07-29

Topics:

Authors:

Clennan, Edward L.

Chen, Xiangning

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00248a044

Replacement of a hydrogen on tetramethylethylene with a variety of functional groups produces a family of substrates which react preferentially with singlet oxygen by abstraction of a geminal hydrogen to form allylic hydroperoxides.

Full text of DOI:10.1021/jo00248a044

Products guided by the article

Product name:2-Methyl-3-(toluene-4-sulfonylmethyl)-but-3-en-2-yl-hydroperoxide

Cas No:114597-44-3

R&D Labs maybe for 114597-44-3

Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo
KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road
Nanjing Samwon International Limited

Contact:+86-25-84873444

Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Wuxi Forest Biological Co.,Ltd

Contact:+86-510-81602300

Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY

Contact:0086-0757-85609331

Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN

Relevant to this article

Solvent enhancement of reaction selectivity: A unique property of cationic chiral dirhodium carboxamidates

Doi:10.1021/ja202676a
(2011)
Design, Synthesis, and Conformational Analysis of Oligobenzanilides as Multifacial α-Helix Mimetics

Doi:10.1021/acs.orglett.9b01115
(2019)
Photolyses of Organocobaloxime Having Aralkyl and (Alkylthio)carbonyl Groups on the β-Position. A Radical Reaction Involving the Thioester Group

Doi:10.1021/ja00222a025
(1988)
Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear Pd^I Catalysis

Doi:10.1002/anie.201906063
(2019)
Facile intramolecular coupling of alkyl and acyl ligands induced by Lewis acids: Mechanistic studies on the formation of zirconium ketone complexes

Doi:10.1021/om00097a028
(1988)
Asymmetric Synthesis and Structure Revision of Guignardone H and I: Development of a Chiral 1,3-Diketone Possessing C₂ Symmetry

Doi:10.1021/acs.orglett.9b00486
(2019)

Article Doi