Geminal Selectivity in Singlet Oxygen Reactions

DOI: 10.1021/jo00248a044

Source and publish data:

Journal of Organic Chemistry p. 3124 - 3125 (1988)

Update date:2022-07-29

Topics:

Authors:

Clennan, Edward L.

Chen, Xiangning

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00248a044

Replacement of a hydrogen on tetramethylethylene with a variety of functional groups produces a family of substrates which react preferentially with singlet oxygen by abstraction of a geminal hydrogen to form allylic hydroperoxides.

Full text of DOI:10.1021/jo00248a044

Products guided by the article

Product name:2-Methyl-3-(toluene-4-sulfonylmethyl)-but-3-en-2-yl-hydroperoxide

Cas No:114597-44-3

R&D Labs maybe for 114597-44-3

Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD
Jiangsu Dacheng Pharmaceutical and Chemical Co.,Ltd

Contact:+86-0517-87036900

Address:Chuzhou Chemical park, Huai'an, Jiangsu Province
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China

Relevant to this article

Solvent enhancement of reaction selectivity: A unique property of cationic chiral dirhodium carboxamidates

Doi:10.1021/ja202676a
(2011)
Design, Synthesis, and Conformational Analysis of Oligobenzanilides as Multifacial α-Helix Mimetics

Doi:10.1021/acs.orglett.9b01115
(2019)
Photolyses of Organocobaloxime Having Aralkyl and (Alkylthio)carbonyl Groups on the β-Position. A Radical Reaction Involving the Thioester Group

Doi:10.1021/ja00222a025
(1988)
Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear Pd^I Catalysis

Doi:10.1002/anie.201906063
(2019)
Facile intramolecular coupling of alkyl and acyl ligands induced by Lewis acids: Mechanistic studies on the formation of zirconium ketone complexes

Doi:10.1021/om00097a028
(1988)
Asymmetric Synthesis and Structure Revision of Guignardone H and I: Development of a Chiral 1,3-Diketone Possessing C₂ Symmetry

Doi:10.1021/acs.orglett.9b00486
(2019)

Article Doi