Geminal Selectivity in Singlet Oxygen Reactions

DOI: 10.1021/jo00248a044

Source and publish data:

Journal of Organic Chemistry p. 3124 - 3125 (1988)

Update date:2022-07-29

Topics:

Authors:

Clennan, Edward L.

Chen, Xiangning

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Article abstract of DOI:10.1021/jo00248a044

Replacement of a hydrogen on tetramethylethylene with a variety of functional groups produces a family of substrates which react preferentially with singlet oxygen by abstraction of a geminal hydrogen to form allylic hydroperoxides.

Full text of DOI:10.1021/jo00248a044

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