Facile intramolecular coupling of alkyl and acyl ligands induced by Lewis acids: Mechanistic studies on the formation of zirconium ketone complexes

DOI: 10.1021/om00097a028

Source and publish data:

Organometallics p. 1631 - 1635 (1988)

Update date:2022-07-29

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Authors:

Waymouth, Robert M.

Grubbs, Robert H.

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Article abstract of DOI:10.1021/om00097a028

Bis(cyclopentadienyl)zirconium acyl complexes Cp₂Zr(X)COR (X = Cl, Me) react rapidly with alkylaluminum reagents R′₂AlY (Y = R′, Cl) to give alkylaluminum adducts of zirconium ketone complexes Cp₂Zr(μ-η²-OCRR′)(

Full text of DOI:10.1021/om00097a028

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