Facile intramolecular coupling of alkyl and acyl ligands induced by Lewis acids: Mechanistic studies on the formation of zirconium ketone complexes

DOI: 10.1021/om00097a028

Source and publish data:

Organometallics p. 1631 - 1635 (1988)

Update date:2022-07-29

Topics:

Authors:

Waymouth, Robert M.

Grubbs, Robert H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00097a028

Bis(cyclopentadienyl)zirconium acyl complexes Cp₂Zr(X)COR (X = Cl, Me) react rapidly with alkylaluminum reagents R′₂AlY (Y = R′, Cl) to give alkylaluminum adducts of zirconium ketone complexes Cp₂Zr(μ-η²-OCRR′)(

Full text of DOI:10.1021/om00097a028

Products guided by the article

Product name:bis(cyclopentadienyl)zirconium(μ-η2-O(13)C(CD3)2)(μ-chloro)Al(i-Bu)2

Cas No:114762-85-5

R&D Labs maybe for 114762-85-5

Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd

Contact:+86-533-5415882

Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Zhejiang Genebest Pharmaceutical Co.,Ltd.

Contact:0086-571-63532866

Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Zhuhai Jiacheng Biological Technology Co., Ltd

Contact:0756-8800233

Address:room 222, Lianhua road , Gongbei ,Zhuhai, Guangdong ,China
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI

Relevant to this article

Palladium-catalyzed cross-couplings of unsaturated halides bearing relatively acidic hydrogen atoms with organozinc reagents

Doi:10.1055/s-0028-1083286
(2009)
REACTION OF ELEMENTAL PHOSPHORUS WITH EPOXIDES

Doi:10.1007/BF00956684
(1987)
Elucidation of the stereostructure of the annonaceous acetogenin (+)-montecristin through total synthesis

Doi:10.1039/b002905j
(2001)
Synthesis of 4-Azidoindole-3-acetic Acid, a Photoprobe Causing Sustained Auxin Activity

Doi:10.1021/jo00251a037
(1988)
A catalytic asymmetric allylation of aldehydes with allyl trichlorosilane activated by a chiral tetradentate bis-sulfoxide

Doi:10.1016/j.tetasy.2009.01.023
(2009)
FACILE MIGRATION OF ACYL GROUPS IN WAGNER-MEERWEIN TRANSPOSITIONS. ACID-CATALYZED REARRANGEMENTS OF 5,6-exo-EPOXY-7-OXA-2-BICYCLO<2.2.1>HEPTANONE AND DERIVATIVES.

Doi:10.1016/S0040-4039(01)81032-7
(1987)

Article Doi