The result demonstrates that the difference in the spacer
significantly affected the sensing function of supramolecular
g-CD complexes for D-glucose. To clarify the spacer effect of
the azoprobes and to gain further efficient sensing ability for
D-glucose as well as to realize supramolecular sensing at
neutral pH, the structural tuning of boronic acid probes are
underway in our laboratory.
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We are grateful for the support by a Grant-in-Aid
(No. 18350043) from the Ministry of Education, Culture,
Sports, Science and Technology, Japan and from the Toray
Scientific Foundation. We also thank Dr R. Kato (Toyohashi
Univ. of Technology) for his support in molecular modeling
calculation.
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