MANIPULATION OF THE CARBOXYL GROUPS OF α-AMINO-ACIDS AND PEPTIDES USING RADICAL CHEMISTRY BASED ON ESTERS OF N-HYDROXY-2-THIOPYRIDONE

DOI: 10.1016/S0040-4020(01)86053-1

Source and publish data:

Tetrahedron p. 5479 - 5486 (1988)

Update date:2022-08-05

Topics:

Authors:

Barton, Derek H. R.

Herve, Yolande

Potier, Pierre

Thierry, Josiane

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Article abstract of DOI:10.1016/S0040-4020(01)86053-1

Photolysis of α-amino-acid or peptide esters derived from N-hydroxy-2-thiopyridone in the presence of t-butylthiol affords the expected decarboxylation products in good yield.The reaction can be applied to the α-carboxyl or to the side chain carboxyl of g

Full text of DOI:10.1016/S0040-4020(01)86053-1

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