Synthesis of silver(I) complexes with carbonyl-stabilized phosphorus ylides: crystal structures of two 2>(1+) derivatives

DOI: 10.1016/0022-328X(87)80012-8

Source and publish data:

Journal of Organometallic Chemistry p. 409 - 421 (1987)

Update date:2022-08-05

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Authors:

Vicente, J.

Chicote, M. T.

Fernandez-Baeza, J.

Martin, J.

Saura-Llamas, L.

Turpin, J.

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Article abstract of DOI:10.1016/0022-328X(87)80012-8

Reactions between AgX (X = ClO4, NO3) and ylides of the type Ph3P=CHC(O)R (R = Me, Ph, OMe, OPh) in the molar ratio 1/2 lead to complexes 2>X; X-ray structure determinations have been carried out on two such complexes (R = OEt, X = ClO4

Full text of DOI:10.1016/0022-328X(87)80012-8

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Product name:((C₆H₅)3P)(CH₃(O)C)HCAg(NO₃)CH(C(O)CH₃)(P(C₆H₅)3)

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