Synthesis of silver(I) complexes with carbonyl-stabilized phosphorus ylides: crystal structures of two 2>(1+) derivatives

Article abstract of DOI:10.1016/0022-328X(87)80012-8

Reactions between AgX (X = ClO4, NO3) and ylides of the type Ph3P=CHC(O)R (R = Me, Ph, OMe, OPh) in the molar ratio 1/2 lead to complexes 2>X; X-ray structure determinations have been carried out on two such complexes (R = OEt, X = ClO4