Synthesis of Proposed Chain-Elongation Intermediates of the Monensin Biosynthetic Pathway

DOI: 10.1021/jo00256a006

Source and publish data:

Journal of Organic Chemistry p. 4923 - 4928 (1988)

Update date:2022-09-26

Topics:

Authors:

Block, Michael H.

Cane, David E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00256a006

Three proposed intermediates of the monensin biosynthetic pathway have been synthesized in 13C-labeled form.Treatment of <2-(13)C>propionyl N-acetylcysteamine (NAC) thioester 10 with 2 equiv of LDA followed by acylation with <1-(13)C>acetyl chloride gave

Full text of DOI:10.1021/jo00256a006

Products guided by the article

Product name:[13C₂]carbomethoxymethylenetriphenylphosphorane

Cas No:116078-37-6

R&D Labs maybe for 116078-37-6

Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Nantong Baokai Chemical Co., Ltd (Hangzhou Baokai Bio-Chemicals Co.,Ltd.)

Contact:+86-513-83886111

Address:No. 68 Suzhou road ,Binjiang Fine Chemical Industrial Park , Beixin town, Qidong city ,Jiangsu province
Jinan Jinguilin Chemical Co.,Ltd

Contact:+86-531-81188412

Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
WENZHOU M&C FOREIGN TRADE CO.,LTD.

Contact:+86-577-88862917

Address:No.8 Liming West Road,Wenzhou,zhejiang,China

Relevant to this article

Straightforward synthesis of the strong ambergris odorant γ-bicyclohomofarnesal and its endo-isomer from R-(+)-sclareolide

Doi:10.1016/S0040-4039(02)01392-8
(2002)
New tetrachlorocyclodiphosph(V)azane complexes of Co(II), Ni(II), and Cu(II): Preparation, characterization, solid state electrical conductivity, and biological activity studies

Doi:10.1080/10426500701839858
(2008)
Synthesis and some pharmacological properties of elatidine derivatives

Doi:10.1023/A:1021892621783
(2002)
Receptor-Specific Delivery of Peptide Nucleic Acids Conjugated to Three Sequentially Linked N-Acetyl Galactosamine Moieties into Hepatocytes

Doi:10.1021/acs.joc.0c00601
(2020)
Reactions of Co-ordinated Ligands. Part 42. The Synthesis and Reactions of Cationic η⁴-Tetraphenylcyclobutadieneruthenium Complexes: X-Ray Crystal Structures of 4-C5H5)> and 5-CH(Ph)C(Ph)C(Ph)C(Ph)O>(η-C5H5)>

Doi:10.1039/DT9870002803
(1987)
Isobutylidenation of 1-C-substituted polyols. Attempted extension of the NMR shift rule via the chemical shift difference of their two methyl groups

Doi:10.1016/0008-6215(94)00297-S
(1995)

Article Doi