Synthesis of Proposed Chain-Elongation Intermediates of the Monensin Biosynthetic Pathway

DOI: 10.1021/jo00256a006

Source and publish data:

Journal of Organic Chemistry p. 4923 - 4928 (1988)

Update date:2022-09-26

Topics:

Authors:

Block, Michael H.

Cane, David E.

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Article abstract of DOI:10.1021/jo00256a006

Three proposed intermediates of the monensin biosynthetic pathway have been synthesized in 13C-labeled form.Treatment of <2-(13)C>propionyl N-acetylcysteamine (NAC) thioester 10 with 2 equiv of LDA followed by acylation with <1-(13)C>acetyl chloride gave

Full text of DOI:10.1021/jo00256a006

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