Synthesis of Proposed Chain-Elongation Intermediates of the Monensin Biosynthetic Pathway

DOI: 10.1021/jo00256a006

Source and publish data:

Journal of Organic Chemistry p. 4923 - 4928 (1988)

Update date:2022-09-26

Topics:

Authors:

Block, Michael H.

Cane, David E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00256a006

Three proposed intermediates of the monensin biosynthetic pathway have been synthesized in 13C-labeled form.Treatment of <2-(13)C>propionyl N-acetylcysteamine (NAC) thioester 10 with 2 equiv of LDA followed by acylation with <1-(13)C>acetyl chloride gave

Full text of DOI:10.1021/jo00256a006

Products guided by the article

Product name:[13C₂]carbomethoxymethylenetriphenylphosphorane

Cas No:116078-37-6

R&D Labs maybe for 116078-37-6

Hebei yanxi chemical co.,LTD.

website:https://en.yan-xi.com/

Contact:+86 17531153977

Address:Zhang zhe, guangzong county, xingtai city, hebei province
Quzhou Ruiyuan chemical Co., Ltd

Contact:+86-570-3039321/3039361/3039308

Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.
HUNAN OUYA BIOLOGICAL CO.,LTD

Contact:+8613400661290

Address:No 908,Kangwan Rd, Liuyang Economic
Linyi Shengxin Pharmaceutical R&D Co., Ltd

Contact:+86-18653953873

Address:West First of Yufeng Road, Yishui County
uni source industries limited

Contact:86 21 3772 9386

Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China

Relevant to this article

Straightforward synthesis of the strong ambergris odorant γ-bicyclohomofarnesal and its endo-isomer from R-(+)-sclareolide

Doi:10.1016/S0040-4039(02)01392-8
(2002)
New tetrachlorocyclodiphosph(V)azane complexes of Co(II), Ni(II), and Cu(II): Preparation, characterization, solid state electrical conductivity, and biological activity studies

Doi:10.1080/10426500701839858
(2008)
Synthesis and some pharmacological properties of elatidine derivatives

Doi:10.1023/A:1021892621783
(2002)
Receptor-Specific Delivery of Peptide Nucleic Acids Conjugated to Three Sequentially Linked N-Acetyl Galactosamine Moieties into Hepatocytes

Doi:10.1021/acs.joc.0c00601
(2020)
Reactions of Co-ordinated Ligands. Part 42. The Synthesis and Reactions of Cationic η⁴-Tetraphenylcyclobutadieneruthenium Complexes: X-Ray Crystal Structures of 4-C5H5)> and 5-CH(Ph)C(Ph)C(Ph)C(Ph)O>(η-C5H5)>

Doi:10.1039/DT9870002803
(1987)
Isobutylidenation of 1-C-substituted polyols. Attempted extension of the NMR shift rule via the chemical shift difference of their two methyl groups

Doi:10.1016/0008-6215(94)00297-S
(1995)

Article Doi