Journal of Organic Chemistry p. 4923 - 4928 (1988)
Update date:2022-09-26
Topics:
Block, Michael H.
Cane, David E.
Three proposed intermediates of the monensin biosynthetic pathway have been synthesized in 13C-labeled form.Treatment of <2-(13)C>propionyl N-acetylcysteamine (NAC) thioester 10 with 2 equiv of LDA followed by acylation with <1-(13)C>acetyl chloride gave
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