STEREOSELECTIVE TOTAL SYNTHESIS OF NATURAL PHYTOL VIA DOUBLE BOND REDUCTIONS BY BAKER'S YEAST

DOI: 10.1016/S0040-4020(01)90325-4

Source and publish data:

Tetrahedron p. 4481 - 4486 (1987)

Update date:2022-08-02

Topics:

Authors:

Gramatica, Paola

Manitto, Paolo

Monti, Diego

Speranza, Giovanna

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)90325-4

Natural (E)-(7R,11R)-phytol (1), a component of the chlorophyll molecule, vitamin K₁ (2) and other natural compounds, was synthesized in enantiomerically and diastereomerically pure form by Li₂CuCl₄-induced coupling of two C₁₀-inits (8,12).Both these units were prepared from geraniol (3) via enzymatic enantioselective hydrogenation of activated double bonds.

Full text of DOI:10.1016/S0040-4020(01)90325-4

Products guided by the article

Product name:methyl (E)-(S)-(+)-3,7-dimethyl-8-<(p-tolylsulphonyl)oxy>-2-octenoate

Cas No:116163-83-8

R&D Labs maybe for 116163-83-8

Changzhou Ruiping Chemical Co., Ltd

website:http://www.wishchem.com

Contact:+86-519-82324280

Address:No.288-1 Huacheng Road, Jintan
Shanghai Send Pharmaceutical Technology Co., Ltd.

website:http://www.shsendpharma.com

Contact:021-58088081, +8613585868794

Address::Room A601, Building 1,NO. 800 Qingdai Road Pudong District Shanghai,China
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu
Sigma-Aldrich Chemie GmbH

website:http://www.sigmaaldrich.com

Contact:800 558-9160

Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
VanderArk International Limited

Contact:86-10-82437576

Address:Qing He

Relevant to this article

Au-catalyzed isomerization of cyclopropenes: a novel approach to indene derivatives

Doi:10.1016/j.tetlet.2009.03.203
(2009)
Synthesis and structures of zinc complexes with new binucleating ligands containing alkoxide bridges, and their activities in the hydrolysis of tris(p-nitrophenyl)phosphate

Doi:10.1016/j.ica.2008.12.012
(2009)
Structure-based insight into the asymmetric bioreduction of the C=C double bond of α,β-unsaturated nitroalkenes by pentaerythritol tetranitrate reductase

Doi:10.1002/adsc.200800561
(2008)
Heterocyclic photochemistry in contrast with carbon behavior. Regioselective photochemical rearrangement of an azacyclohexadienone: Mechanistic and exploratory organic photochemistry

Doi:10.1021/jo900901g
(2009)
A Catalytic Reductive Cyclization of 1,6-Diynes

Doi:10.1021/ja00229a073
(1988)
Synthesis, characterization, and substituent effects of mononuclear ruthenium complexes [RuCl(CO)(PMe₃)₃(CH{double bond, long}CH-C₆H₄-R-p)] (R = H, CH₃, OCH₃, NO₂, NH₂

Doi:10.1016/j.jorganchem.2009.01.024
(2009)

Article Doi