STEREOSELECTIVE TOTAL SYNTHESIS OF NATURAL PHYTOL VIA DOUBLE BOND REDUCTIONS BY BAKER'S YEAST

DOI: 10.1016/S0040-4020(01)90325-4

Source and publish data:

Tetrahedron p. 4481 - 4486 (1987)

Update date:2022-08-02

Topics:

Authors:

Gramatica, Paola

Manitto, Paolo

Monti, Diego

Speranza, Giovanna

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)90325-4

Natural (E)-(7R,11R)-phytol (1), a component of the chlorophyll molecule, vitamin K₁ (2) and other natural compounds, was synthesized in enantiomerically and diastereomerically pure form by Li₂CuCl₄-induced coupling of two C₁₀-inits (8,12).Both these units were prepared from geraniol (3) via enzymatic enantioselective hydrogenation of activated double bonds.

Full text of DOI:10.1016/S0040-4020(01)90325-4

Products guided by the article

Product name:methyl (E)-(S)-(+)-3,7-dimethyl-8-<(p-tolylsulphonyl)oxy>-2-octenoate

Cas No:116163-83-8

R&D Labs maybe for 116163-83-8

Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China
Shanghai Demand Chemical Co., ltd，China

Contact:86-021-55237578/55239122

Address:Room 3H, No.578, Yingkou Road, Yangpu District, Shanghai, China
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
Shenzhen JYMed Technology Co.,Ltd.

website:http://www.jymedtech.com

Contact:+86-755-26612112

Address:1#8,9/F, Biomedicine innovation Industrial Park, No.14, Jinhui Road, Pingshan Sistrict, Shenzhen, China
Jiangsu Feymer Technology Co., Ltd.

Contact:+86-512-58110132

Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China

Relevant to this article

Au-catalyzed isomerization of cyclopropenes: a novel approach to indene derivatives

Doi:10.1016/j.tetlet.2009.03.203
(2009)
Synthesis and structures of zinc complexes with new binucleating ligands containing alkoxide bridges, and their activities in the hydrolysis of tris(p-nitrophenyl)phosphate

Doi:10.1016/j.ica.2008.12.012
(2009)
Structure-based insight into the asymmetric bioreduction of the C=C double bond of α,β-unsaturated nitroalkenes by pentaerythritol tetranitrate reductase

Doi:10.1002/adsc.200800561
(2008)
Heterocyclic photochemistry in contrast with carbon behavior. Regioselective photochemical rearrangement of an azacyclohexadienone: Mechanistic and exploratory organic photochemistry

Doi:10.1021/jo900901g
(2009)
A Catalytic Reductive Cyclization of 1,6-Diynes

Doi:10.1021/ja00229a073
(1988)
Synthesis, characterization, and substituent effects of mononuclear ruthenium complexes [RuCl(CO)(PMe₃)₃(CH{double bond, long}CH-C₆H₄-R-p)] (R = H, CH₃, OCH₃, NO₂, NH₂

Doi:10.1016/j.jorganchem.2009.01.024
(2009)

Article Doi