STEREOSELECTIVE TOTAL SYNTHESIS OF NATURAL PHYTOL VIA DOUBLE BOND REDUCTIONS BY BAKER'S YEAST

DOI: 10.1016/S0040-4020(01)90325-4

Source and publish data:

Tetrahedron p. 4481 - 4486 (1987)

Update date:2022-08-02

Topics:

Authors:

Gramatica, Paola

Manitto, Paolo

Monti, Diego

Speranza, Giovanna

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Article abstract of DOI:10.1016/S0040-4020(01)90325-4

Natural (E)-(7R,11R)-phytol (1), a component of the chlorophyll molecule, vitamin K₁ (2) and other natural compounds, was synthesized in enantiomerically and diastereomerically pure form by Li₂CuCl₄-induced coupling of two C₁₀-inits (8,12).Both these units were prepared from geraniol (3) via enzymatic enantioselective hydrogenation of activated double bonds.

Full text of DOI:10.1016/S0040-4020(01)90325-4

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