Organic Letters p. 6048 - 6051 (2014)
Update date:2022-07-29
Topics:
Kwon, Ki-Hyeok
Serrano, Catherine M.
Koch, Michael
Barrows, Louis R.
Looper, Ryan E.
A cascade silver(I)-catalyzed hydroamination/Michael addition sequence has been developed to deliver highly substituted bicyclic guanidines. This transformation gives rise to geometrically and constitutionally stable ene-guanidines and generates a remote stereocenter with moderate to high diastereoselectivity.
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