ET3B Induced Stereoselective Radical Addition of Ph3GeH to Acetylenes and its Application to Isomerization of Olefins

DOI: 10.1016/S0040-4039(00)96363-9

Source and publish data:

Tetrahedron Letters p. 3709 - 3712 (1987)

Update date:2022-07-29

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Authors:

Ichinose, Yoshifumi

Nozaki, Kyoko

Wakamatsu, Kuni

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)96363-9

Triphenylgermane adds easily to acetylenes in the presence of Et₃B to give (E)- or (Z)-alkenyltriphenylgermanes, respectively, under excellent control of regio- and stereoselectivities.

Full text of DOI:10.1016/S0040-4039(00)96363-9

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