SILICON PUMMERER REACTION OF THIAZOLIDINE S-OXIDES; A NEW METHOD FOR STEREOSPECIFIC C-5 FUNCTIONALIZATION OF THIAZOLIDINES

Article abstract of DOI:10.1016/S0040-4039(01)81086-8

Silicon Pummerer reaction of optically active thiazolidine S-oxides using trialkylsilyl triflate led to a stereospecific formation of α-siloxysulfides, while the use iodotrimethylsilane resulted in a facile formation of α-iodosulfides.