SYNTHESIS OF METHYL 6"-DEOXY-6'-FLUORO-α-ISOMALTOSIDE AND OF THE CORRESPONDING TRISACCHARIDE

Article abstract of DOI:10.1016/0008-6215(88)84143-0

Methyl 6-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside (5) was formed with high stereoselectivity when the condensation of methyl 2,3,4-tri-O-benzyl-α-D-glucopyranosyl (1) with 6-O-acetyl-2,3,4-tri-O-benzyl-α-