A NEW AND FACILE PERHYDROAZULENE FORMATION: THE TOTAL SYNTHESIS OF THE CAROTANE (+)-DAUCENE

DOI: 10.1016/S0040-4020(01)87740-1

Source and publish data:

Tetrahedron p. 5593 - 5604 (1987)

Update date:2022-07-31

Topics:

Authors:

Audenaert, Frans

Keukeleire, Denis De

Vandewalle, Maurits

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Article abstract of DOI:10.1016/S0040-4020(01)87740-1

Thermolysis of the 2,5-bis(trimethylsiloxy)tricyclo<4.4.0.0^2,5>decan-7-ones 3 leads to perhydroazulenes by a transannular reaction involving an oxygen to oxygen migration of a silyl group in the intermediate cyclodecadienones.This 3-step transf

Full text of DOI:10.1016/S0040-4020(01)87740-1

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