Tetrahedron p. 5593 - 5604 (1987)
Update date:2022-07-31
Topics:
Audenaert, Frans
Keukeleire, Denis De
Vandewalle, Maurits
Thermolysis of the 2,5-bis(trimethylsiloxy)tricyclo<4.4.0.02,5>decan-7-ones 3 leads to perhydroazulenes by a transannular reaction involving an oxygen to oxygen migration of a silyl group in the intermediate cyclodecadienones.This 3-step transf
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