E- OR Z-SELECTIVE HORNER-WITTIG REACTIONS OF SUBSTITUTED BICYCLOOCTANE-3-ONES WITH CHIRAL PHOSPHONOACETATES

DOI: 10.1016/S0040-4039(00)82040-7

Source and publish data:

Tetrahedron Letters p. 1775 - 1776 (1988)

Update date:2022-08-04

Topics:

Authors:

Rehwinkel, Hartmut

Skupsch, Juergen

Vorbrueggen, Helmut

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)82040-7

The Horner-Wittig reaction of substituted bicyclo(3.3.0)octane-3-ones with chiral phosphonoacetates 2 gave the corresponding unsaturated esters in E/Z-ratios of up to 91 : 9.

Full text of DOI:10.1016/S0040-4039(00)82040-7

Products guided by the article

Product name:[(3aS,4S,5R,6aS)-5-Hydroxy-4-((3S,4S)-3-hydroxy-4-methyl-nona-1,6-diynyl)-hexahydro-pentalen-(2E)-ylidene]-acetic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester

Cas No:117109-80-5

R&D Labs maybe for 117109-80-5

SHANGHAI SYSTEAM BIOCHEM CO., LTD

website:http://www.systeambc.com

Contact:86-021-58380978

Address:Building 87，Lane 669， Dong Jing Road Shanghai,P.R.China
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou
Zhejiang Allied Chemical Co.,Ltd

Contact:18967038207

Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China

Relevant to this article

Synthesis and characterisation of hexa- and tetrasaccharide mimics from acetobromomaltotriose and acetobromomaltose, and of C-disaccharide mimics from acetobromoglucose, obtained by electrochemical reduction on silver

Doi:10.1016/j.tetasy.2004.11.052
(2005)
Generation and in situ evaluation of libraries of poly(acrylic acid) presenting sialosides as side chains as polyvalent inhibitors of influenza- mediated hemagglutination

Doi:10.1021/ja963519x
(1997)
Synthesis of the thio-linked ganglioside GM₃ epitope

Doi:10.1002/jlac.199719970512
(1997)
General synthetic route to substituted bis(cyclopentadienyl)- and bis(indenyl)methanes

Doi:10.1055/s-1997-1200
(1997)
Synthesis of 3-trialkylsilyl pyrazoles from β-oxo acylsilanes

Doi:10.1016/S0040-4039(00)01724-X
(2000)
Lead optimization generates selenium-containing miconazole CYP51 inhibitors with improved pharmacological profile for the treatment of fungal infections

Doi:10.1016/j.ejmech.2021.113337
(2021)

Article Doi