Synlett p. 1303 - 1306 (2009)
Update date:2022-07-30
Topics: Retrosynthetic analysis Purification and characterization Ring-Closing Metathesis (RCM) Chiral Control Further Elaboration Formation of Key Intermediate Repetition and Building Blocks Completion and Optimization
Kim, Myung-Yeol
Kim, Hyemi
Tae, Jinsung
A highly efficient asymmetric total synthesis of (+)-brefeldin A was accomplished by using intramolecular epoxide opening of an epoxy allylsilane and RCM reaction for the constructions of the cyclopentane and macrocyclic lactone rings of (+)-brefeldin A,
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