The Crystal Structure, Absolute Configuration and Circular Dichroism of (-)CD630- and (+)CD630-cis-Bisdichloroplatinum(II)*ethanol

DOI: 10.1246/cl.1988.1479

Source and publish data:

Chemistry Letters p. 1479 - 1482 (1988)

Update date:2022-08-03

Topics:

Authors:

Furuhashi, Akiko

Endo, Kunihiko

Ouchi, Akira

Saito, Yoshihiko

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Article abstract of DOI:10.1246/cl.1988.1479

The crystals of the title complex resolve spontaneously.The enantiomeric crystals were separated under a microscope.They are orthorhombic, space group P2₁2₁2₁.This is a square planar complex with 2Cl in cis-positions.The ligand acts as a unidentate with its N atom.The absolute configuration was correlated with the CD spectrum in microcrystalline state.

Full text of DOI:10.1246/cl.1988.1479

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