Iterative, Stereoselective Homologation of Chiral Polyalkoxy Aldehydes Employing 2-(Trimethylsilyl)thiazole as a Formyl Anion Equivalent. The Thiazole Route to Higher Carbohydrates

DOI: 10.1021/jo00264a035

Source and publish data:

Journal of Organic Chemistry p. 693 - 702 (1989)

Update date:2022-08-05

Topics:

Authors:

Dondoni, Alessandro

Fantin, Giancarlo

Fogagnolo, Marco

Medici, Alessandro

Pedrini, Paola

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00264a035

A new approach to long-chain sugars is demonstrated by the stereoselective conversion of D-glyceraldehyde acetonide (2a), L-threose acetonide (2b), and dialdogalactopyranose diacetonide (2h) into higher homologues up to C₉, C₇, and C

Full text of DOI:10.1021/jo00264a035

Products guided by the article

Product name:(1R)-1,4-di-O-benzyl-2,3-O-isopropylidene-1-(2-thiazolyl)-L-threiotol

Cas No:118377-13-2

R&D Labs maybe for 118377-13-2

Jinan Kaypharm Chemical Co.,Ltd

Contact:86-0531-86986780

Address:Room101,No189-2,Huayuan Road,Jinan City,Shandong Province
jintan yufan Medicine Raw materials Co.,Ltd.(expird)

Contact:86-519-82808282

Address:6th,Jincheng Huangzhuang
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Nanjing Legend Pharmaceutical & Chemical Co., Ltd.

Contact:+86-25-83767696

Address:14-7 Zhongshan Lu Guluo District, Nanjing
Weifang Ocean Trading Co., Ltd.

Contact:+86-536-2081155

Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China

Relevant to this article

Practical catalytic asymmetric synthesis of diaryl-, aryl heteroaryl-, and diheteroarylmethanols

Doi:10.1021/ja9046747
(2009)
Template-directed synthesis of a covalent organic capsule based on a 3 nm-sized metallocapsule

Doi:10.1021/ja903324r
(2009)
Highly efficient organocatalyzed direct asymmetric aldol reactions of hydroxyacetone and aldehydes

Doi:10.1002/adsc.200800558
(2009)
Organocatalytic activity of cinchona alkaloids: Which nitrogen is more nucleophilic?

Doi:10.1021/jo901670w
(2009)
Polypeptide dendrimers: Self-assembly and drug delivery

Doi:10.1007/s11426-010-4218-2
(2011)
Nucleophilic ring opening of mono-activated cyclopropanes with arylselenolates generated from diselenides in the presence of a Zn/AlCl ₃ system

Doi:10.1055/s-0029-1217372
(2009)

Article Doi