Iterative, Stereoselective Homologation of Chiral Polyalkoxy Aldehydes Employing 2-(Trimethylsilyl)thiazole as a Formyl Anion Equivalent. The Thiazole Route to Higher Carbohydrates

DOI: 10.1021/jo00264a035

Source and publish data:

Journal of Organic Chemistry p. 693 - 702 (1989)

Update date:2022-08-05

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Authors:

Dondoni, Alessandro

Fantin, Giancarlo

Fogagnolo, Marco

Medici, Alessandro

Pedrini, Paola

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Article abstract of DOI:10.1021/jo00264a035

A new approach to long-chain sugars is demonstrated by the stereoselective conversion of D-glyceraldehyde acetonide (2a), L-threose acetonide (2b), and dialdogalactopyranose diacetonide (2h) into higher homologues up to C₉, C₇, and C

Full text of DOI:10.1021/jo00264a035

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