Chemistry Letters p. 977 - 980 (1988)
Update date:2022-08-02
Topics:
Tanikaga, Rikuhei
Hamamura, Kazumasa
Kaji, Aritsune
Dianions generated from β-hydroxysulfoxides reacted with n-C8H17I, n-C9H19CHO, and D2O to give products in different threo/erythro ratios, but those ratios were found to be essentially same in the early stage.The configurational interconversion of the diastereoisomeric carbanions would play an important role.
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