Crystal and Molecular Structure of the 2:1 Charge-Transfer Salt of Decamethylferrocene and Perfluoro-7,7,8,8-tetracyano-p-quinodimethane: .+>22-. Electronic Structure of n (n = 0, 1-, 2-)

Article abstract of DOI:10.1021/j100343a019

The reaction of decamethylferrocene, Fe(C5Me5)2, and perfluoro-7,7,8,8-tetracyano-p-quinodimethane, TCNQF4, leads to the isolation of two phases of 1:1 and 2:1 stoichiometry.The crystal and molecular structure of the black 2:1 substance has been determine