Effects of Aryl Substituents on Electron-Transfer-Mediated Photochemical Addition of Alcohol to 1,1,2-Triarylcyclopropanes

DOI: 10.1246/bcsj.61.1404

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1404 - 1406 (1988)

Update date:2022-08-04

Topics:

Authors:

Tomioka, Hideo

Inoue, Osamu

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Article abstract of DOI:10.1246/bcsj.61.1404

Direct irradiation of 1,1,2-triarylcyclopropanes in alcohol resulted in the formation of all possible products arising from trimethylene biradicals, while DCB-sensitised irradiation gave a novel "anti-Markownikoff" addition product of alcohol almost exclusively.In order to get insight into the nature and fate of intermediates in the reactions, the effects of nucleophiles and aryl substituents are examined.

Full text of DOI:10.1246/bcsj.61.1404

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