Effects of Aryl Substituents on Electron-Transfer-Mediated Photochemical Addition of Alcohol to 1,1,2-Triarylcyclopropanes

DOI: 10.1246/bcsj.61.1404

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1404 - 1406 (1988)

Update date:2022-08-04

Topics:

Authors:

Tomioka, Hideo

Inoue, Osamu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.61.1404

Direct irradiation of 1,1,2-triarylcyclopropanes in alcohol resulted in the formation of all possible products arising from trimethylene biradicals, while DCB-sensitised irradiation gave a novel "anti-Markownikoff" addition product of alcohol almost exclusively.In order to get insight into the nature and fate of intermediates in the reactions, the effects of nucleophiles and aryl substituents are examined.

Full text of DOI:10.1246/bcsj.61.1404

Products guided by the article

Product name:1-ethoxy-1,3,3-triphenylpropane

Cas No:118468-44-3

R&D Labs maybe for 118468-44-3

TIC Gums, Inc.

Contact:410-273-7300; 800-221-3953

Address:4609 Richlynn Dr., PO Box 369, Belcamp, MD, 21017-0369, USA
Changzhou Ruiping Chemical Co., Ltd

website:http://www.wishchem.com

Contact:+86-519-82324280

Address:No.288-1 Huacheng Road, Jintan
Xinjiang Zhongtai Chemical Co., Ltd.

Contact:+86-991-8788172

Address:NO.78 XISHAN RD.URUMQI，CHINA
Zhejiang Genebest Pharmaceutical Co.,Ltd.

Contact:0086-571-63532866

Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
Anhui Sunsing Chemicals Co.,Ltd

website:http://www.sunsingchem.com

Contact:0086-566-2023179

Address:Jin An industry park, Chizhou economic technical development zone, Anhui

Relevant to this article

Β-1,2,3-triazolyl-nucleosides as nicotinamide riboside mimics

Doi:10.1080/15257770902865415
(2009)
Electrochemical, Spectroelectrochemical, and Structural Studies of Mono- and Diphosphorylated Zinc Porphyrins and Their Self-Assemblies

Doi:10.1021/acs.inorgchem.9b00268
(2019)
Copper-catalyzed difunctionalization of activated alkynes by radical oxidation-tandem cyclization/dearomatization to synthesize 3-trifluoromethyl spiro[4.5]trienones

Doi:10.1002/chem.201405672
(2015)
Selective synthesis of 3-aryl quinolin-2(1H)-ones and 3-(1-arylmethylene) oxindoles involving a 2-fold arene C-H activation process

Doi:10.1021/jo901314t
(2009)
Tumour regression and improved gastrointestinal tolerability from controlled release of SN-38 from novel polyoxazoline-modified dendrimers

Doi:10.1016/j.jconrel.2016.12.034
(2017)
Reactivity Patterns in the Rhodium Carbenoid Induced Tandem Cyclization-Cycloaddition Reaction

Doi:10.1021/jo00265a019
(1989)

Article Doi