Bulletin of the Chemical Society of Japan p. 1404 - 1406 (1988)
Update date:2022-08-04
Topics:
Tomioka, Hideo
Inoue, Osamu
Direct irradiation of 1,1,2-triarylcyclopropanes in alcohol resulted in the formation of all possible products arising from trimethylene biradicals, while DCB-sensitised irradiation gave a novel "anti-Markownikoff" addition product of alcohol almost exclusively.In order to get insight into the nature and fate of intermediates in the reactions, the effects of nucleophiles and aryl substituents are examined.
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